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Acetic (Vinegar) Syndrome
                                                               – A UK Perspective
                                     by Rob Foxon
        Despite much investigation in the past by   can only attempt to slow the process down by
        chemists and the wider academic community,   understanding the problem and managing it
        there is no agreement on what actually triggers   accordingly. All chemical processes are slowed
        acetic syndrome in film stock, so we have to   by a reduction in temperature. In an archive,
        judge the  probable cause(s) from  experience.   films are stored in temperature and humidity
        What we do know is that acetic syndrome is a   controlled vaults, but keeping films cool is not
        degenerative chemical process and that acetate   always easy to achieve for the collector.
        film is hygroscopic (it absorbs moisture and
        gas).













                          Stage 3/4: The film becomes distorted and twisted.
        When a film  becomes acetic, it  gives off the   Briefly, the acetic process can be observed and
        familiar vinegar smelling gas and must be iso-  classified into four stages:
        lated from other films immediately or there is   Stage 1: The film becomes infected and devel-
        the potential for them to absorb it, thus spread-  ops the familiar vinegar  smell.  It is however
        ing the                 problem like   otherwise fine and can still be projected nor-
                                a virus.    mally. It will likely remain so for a long period
                                            of time so enjoy, but isolate from the rest of the
                                 When a film   collection.
                                 becomes
                                 acetic, the   Stage 2:   The smell is more intense. The film
                                 film base is   becomes twisty but is still projectable.
                                 affected, the
                                 image  re-  Stage 3:   The film base begins to curl up, start-
                                 mains  but  ing from the perforation edge. The film is no
                                 becomes    longer projectable and the end is nigh!
                                 distorted as
                                 the stability   Stage 4: Film base distorts severely, then crys-
                                 of the  film   tallises to powder; total destruction. In the UK
                                 base wors-  climate, this whole process can take upwards of
                                 ens. There is   20 years.
                                 no  known
                                 cure so one

                               Left:   Stage 4:    Heavy decomposition of the film base.
                               It’s Kodak 1937 B/W stock.     The end!

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